cis-Aquadichlorido[pyrimidin-2(1H)-one-κN3]copper(II)

cis-Aquadichlorido[pyrimidin-2(1H)-one-κN3]copper(II)

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In the title compound, g35 coupe fender [CuCl2(C4H4N2O)(H2O)], the CuII cation is coordinated by two chloride anions, one pyrimidin-2-one N atom and one water molecule, giving a slightly distorted square-planar geometry.In the crystal structure, the pyrimidin-2-one rings stack along the b axis, with an interplanar distance of 3.306 Å, as do the copper coordination planes (interplanar spacing = 2.998 Å).

The coordination around the Jahn–Teller-distorted CuII ion is completed by long Cu.O [3.014 (5) Å] and Cu.Cl [3.

0194 (15) Å] interactions with adjacent molecules involved in this stacking.Several N—H.Cl, O—H.Cl umcka where to buy and O—H.

O intermolecular hydrogen bonds form a polar three-dimensional network.